— In each experiment small grains < 100 μm of calcite dolomite and magnesite and a ruby sphere were individually loaded into four holes of a gasket respectively Figure S1 then a drop of deionized water MΩ cm with neutral pH pH = 23 °C and 1 atm was quickly loaded in all holes at the same time as the pressure
— A combined high pressure mid infrared absorption and Raman spectroscopy study on a natural CO3 2 dolomite sample was performed both at ambient and high temperatures
Yêu cầu trực tuyến →— In addition a local distortion of the ambient pressure dolomite structure was identified close to 11 GPa just before the transition toward the first known high pressure phase All the Clausius
Yêu cầu trực tuyến →In this study we investigated four different ferroan dolomite samples using in situ Raman spectroscopy and powder X ray diffraction XRD at pressures up to 48 GPa and room temperature Our results show that the transition from Dolomite I Dol I to Dolomite II Dol II occurs above 13 16 GPa and the transition pressure depends on the composition of
Yêu cầu trực tuyến →— Synchrotron single crystal X ray diffraction experiments at high pressure and high temperature conditions were performed up to 20 GPa and 2 K on a fully ordered stoichiometric dolomite and a partially disordered stoichiometric dolomite [order parameter s = 6 ] The ordered dolomite was found to be stable up to approximately 14 GPa at
Yêu cầu trực tuyến →— The stability of Fe poor dolomite CO3 2 was studied by Raman spectroscopy and single crystal X ray diffraction at high pressures P < 60 GPa and high temperatures T < 2300 K
Yêu cầu trực tuyến →— It transforms above 35 GPa to dolomite III also triclinic which features carbon in [3 1] coordination at the highest pressures investigated 60 GPa The structure is therefore representative of an intermediate between the low pressure carbonates and the predicted ultra high pressure carbonates with carbon in tetrahedral coordination
Yêu cầu trực tuyến →— The most commonly used best value for dolomite solubility in water is based on HCI solution calorimetry at K which is not confirmed by earlier determinations based on heat capacity of
Yêu cầu trực tuyến →— Indeed due to the difficulty of precipitating dolomite in the laboratory questions surrounding its crystallinity and other experimental challenges including controlling experimental CO 2 partial pressure and the measurement of pH and alkalinity above ambient temperatures there is a wide disparity in the values of the dolomite
— Ab initio calculations were performed on ordered and disordered dolomite and dolomite II crystal structures The mechanism for the dolomite to dolomite II phase transition was investigated by the calculation of vibrational frequencies In particular a soft mode was observed at the F point of the rhombohedral Brillouin zone whose frequency
Yêu cầu trực tuyến →— The infrared and x‐ray data are consistent with dolomite adopting a calcite‐III‐like structure Our results indicate that high‐pressure polymorphism in dolomite could stabilize CaMg CO3 2 in the deep mantle and thus that high‐pressure polymorphs of dolomite could represent the main reservoir for carbon storage within Earth s lower
One does not even know for certain that dolomite rather than a mineral pair calcite magnesite or calcite nesquehonite is the stable phase under room temperatures and atmospheric pressures The published results of the solubility of dolomite at 25 "C and a pressure of 1 atm differ by as much as three orders of magnitude
Yêu cầu trực tuyến →— Marble is a granular metamorphic rock it is derived from limestone or dolomite and It consists of a mass of interlocking grains of calcite or the mineral dolomite Form of it when limestone buried deep in the older layers of Earth s crust is subjected to heat and pressure from thick layers of overlying sediments
Yêu cầu trực tuyến →— As high pressure polymorphs of dolomite and ferroan dolomite co uld represent a 90 reservoir for carbon storage with in the deep mantle it is impo rtant to study the high 91
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